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KMID : 1171820090240010033
Journal of Environmental and Sanitary Engineering
2009 Volume.24 No. 1 p.33 ~ p.39
Effect of Metal ion on Rancidity of Crude Rapeseed Oil
Kim Youn-Soon

Kim Yoon-Soo
Nam Hyung-Gun
Seo Gwang-Yeob
Abstract
In order to investigate effect of metal ion and antioxidant on rancidity of crude rapeseed oil (CRO), Fe©÷?, Cu©÷?, Co©÷?, Ni©÷?, Cr©÷?, Sn©÷?, Mn©÷?, Zn©÷?, and antioxidants including BHA, Vitamin C, and Tocopherol were used. The specific gravity and refractive index of CRO were 0.92g/§¨ and 1.45,respectively.
The chromaticities of light, red, and yellow in CRO were 88.6 and 98.7, respectively. Among various fatty acids, Oleic acid (C18:1) concentration was highest, 62.3% and Linoleic acid (C18:2) concentration was 19.16%. In the case of Linolenic acid (C18:3) and Palmitic acid (C16:0), they were 9.88 and 5.2%, respectively. The concentrations of unsaturated fatty acids and saturated fatty acid were 92.2 and 7.8%, respectively. The degree of expediting rancidity of CRO was an order of Fe©÷?£¾ Cu©÷?£¾ Cr©÷?£¾ Zn©÷?£¾ Ni©÷?£¾ Al©÷?£¾ Mn©÷?£¾ Mn©÷?£¾ Sn©÷?£¾ Co©÷?£¾ Li©÷?. Especially, when Cu©÷? and Fe©÷? was used, the peroxide value concentration was about 4.0 fold higher than non addition of them. The inhibition effect of rancidity of CRO using antioxidant with Cu©÷? and Fe©÷? was an order of BHA£¾ Vitamin C£¾Tocopherol.
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